Phlogiston was the eighteenth century’s answer to the Elemental Fire of the Greek alchemists. Ignite wood, and let it burn. What is the orangey-bright “fire” stuff? Why does the wood transform into ash? To both questions, the eighteenth-century chemists answered, “phlogiston.”

. . . and that was it, you see, that was their answer: “Phlogiston.”

Phlogiston escaped from burning substances as visible fire. As the phlogiston escaped, the burning substances lost phlogiston and so became ash, the “true material.” Flames in enclosed containers went out because the air became saturated with phlogiston, and so could not hold any more. Charcoal left little residue upon burning because it was nearly pure phlogiston.

Of course, one didn’t use phlogiston theory to predict the outcome of a chemical transformation. You looked at the result first, then you used phlogiston theory to explain it. It’s not that phlogiston theorists predicted a flame would extinguish in a closed container; rather they lit a flame in a container, watched it go out, and then said, “The air must have become saturated with phlogiston.” You couldn’t even use phlogiston theory to say what you ought not to see; it could explain everything.

This was an earlier age of science. For a long time, no one realized there was a problem. Fake explanations don’t feel fake. That’s what makes them dangerous.

Modern research suggests that humans think about cause and effect using something like the directed acyclic graphs (DAGs) of Bayes nets. Because it rained, the sidewalk is wet; because the sidewalk is wet, it is slippery:

From this we can infer—or, in a Bayes net, rigorously calculate in probabilities—that when the sidewalk is slippery, it probably rained; but if we already know that the sidewalk is wet, learning that the sidewalk is slippery tells us nothing more about whether it rained.

Why is fire hot and bright when it burns?

It feels like an explanation. It’s represented using the same cognitive data format. But the human mind does not automatically detect when a cause has an unconstraining arrow to its effect. Worse, thanks to hindsight bias, it may feel like the cause constrains the effect, when it was merely fitted to the effect.

Interestingly, our modern understanding of probabilistic reasoning about causality can describe precisely what the phlogiston theorists were doing wrong. One of the primary inspirations...

Davis

Davis

Davis

Davis